Thank you for clarifying your question!
First, let's clear up a significant point from the examples above: in the example where I introduced roses, I did not say that roses were the same thing as "B". It's an entirely separate category, one that partially overlaps A and B. Check out the diagram that illustrates this.
As you can see, most A are B. As a completely separate matter, it just so happens that most A are also roses. But there are some roses that aren't Bs, and some Bs that aren't roses. Take Joe, for instance. He's an A, and he's a rose, but he's no B!
So why do we care? Well, the original statement that you wanted to infer was "If you are not a B, then you are not in the category that most As are in." Okay, so Joe is not a B. Is it true that he is not in "the category that most As are in"? Well, he's not in the B category, which most As are in. But he could be in the 'rose category' (as he is in our diagram), and most As are in that!
We cannot, therefore, infer a blanket statement such as "Joe is different from most As" - different how? That statement would suggest he's different in *every* way! You could say something very narrow and specific, such as "with respect to the question of B-ness, Joe differs from most As". But that's all.
Let's take your later example and adjust it. Let's say most Americans like ice cream. As a separate matter, most Americans like pizza. But the pizza lovers and the ice cream fiends are not the exact same group.
Now, Joe likes ice cream, just like most Americans. But he abhors pizza. So,
with respect to the question of liking pizza, he is not in the category that most Americans are in. But
with respect to the question of liking ice cream, he is! So, if all we knew about Joe was that he didn't like pizza, we can't conclude much about his relation to most Americans - there are millions of other potential categories where he might be like, or not like, most Americans.
While the statement "with respect to the question of liking pizza, Joe is not in the category that most Americans are in" is arguably a technically valid statement, it would not be called a 'contrapositive'. But more importantly, it's not that useful of a statement. We cannot use that statement to lead us anywhere new, and we are unlikely to be able to link it to, or combine it with other statements to understand something interesting about our players the way we can with the contrapositive of a conditional statement.
All we've really done is torture a 'most' statement into a very narrow grammatical pretzel. It is a rather interesting linguistic exercise, but it's not likely to help you score points on the LSAT.
The key points to remember about most statements are:
If most A are B1) Some A are B
2) Some B are A
3) It's possible that all A are B (but you don't know!)
4) You cannot say that most B are
anything5) You cannot say that most -A are
anything6) You cannot say that most -B are
anythingI hope that this helps clarify the issue! Please let me know if you have additional questions!